In the process of dynamic Measurement While Drilling (MWD), the strong vibration and rapid rotation of the Bottom Hole Assembly (BHA) lead to multi-frequency and high-amplitude noise interference in the attitude measurement signal. The weak original signal and extremely low signal-to-noise ratio (SNR) are always the technical difficulties of dynamic MWD. To solve this problem, this paper uses the chaotic effect of the Duffing system, which takes the expression (−x3 + x5) as a nonlinear restoring force to detect the weak characteristic signal of downhole dynamic MWD. First of all, in order to meet the limit condition of the chaotic phase transition of the system output, the frequency value of the characteristic signal is reconstructed and transformed based on the variable scale theory. Then, in order to solve the influence of the initial phase of the characteristic signal on the detection accuracy, a detection model based on the array Duffing system is presented, and a frequency-detection scheme with all-phase coverage is given. Finally, another array Duffing system is designed for the parameter estimation of the characteristic signal. The critical value of chaotic phase transition is determined by adjusting the amplitude of the driving signal of the array Duffing system, and then the amplitude and phase parameters of the characteristic signal are synchronously estimated. The experimental results show that the proposed method can effectively extract the weak characteristic signal within the strong noise, and the SNR of the characteristic signal can be as low as −21 dB. Through the attitude calculation for the extracted characteristic signal, it can be seen that the proposed method can improve the accuracy of the inclination of the drilling tool significantly, which proves the feasibility and effectiveness of the method proposed in this paper.