“…In past years, different types of materials have been employed as CML (Figure 1), such as ambipolar hosts, electron transporting materials, hole transporting materials, and mixed or blend inter-layer of hole and electron transporting materials. Several research groups have extensively employed numerous types of blend/mixed inter-layer or hybrid spacer, such as 4,4′′-di(triphenylsilyl)-p-terphenyl (BSB):2,7-bis(9-carbazolyl)-9,9-spirobifluorene (Spiro-2CBP) [44], 4, 4′- N , N ′-dicarbazole-biphenyl (CBP):4,7-diphenyl-1,10-phenanthroline (BPhen) [47], CBP:2-methyl-9,10-bis(naphthalen-2-yl)anthracene (MADN) [48], 4,4′,4′-tris( N -carbazolyl)-triphenylamine (TCTA):1,3,5-tris[ N -(phenyl)benzimidazole]benzene (TPBi) [49], TCTA:BPhen, TCTA:bis-(2-methyl-8-quinolinolate)-4-(phenylphenolato)aluminium (BAlq) [50], TCTA:bis[2-(2-hydroxyphenyl)-pyridine] beryllium (Bepp 2 ) [51], N , N ′-dicarbazolyl-3,5-benzene (mCP):BPhen, and BH046:BPhen, between the emissive layers to achieve high efficiency, high brightness, very high color rendering index (CRI) and long lifetime OLEDs [44,47,48,49,50,51,52,53,54,55,56]. We have summarized the triplet energy (E T ), optical energy band gap (E g ), highest occupied molecular orbitals (HOMO), lowest unoccupied molecular orbitals, hole mobility (μ h ), and electron mobility (μ e ) of carrier modulation materials in Table 1.…”