2013
DOI: 10.1016/j.memsci.2013.04.009
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Rational design of phase inversion membranes by tailoring thermodynamics and kinetics of casting solution using polymer additives

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Cited by 282 publications
(172 citation statements)
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“…Furthermore, the shift of the binodal curves in PES/metal nanoparticles membranes in the cloud point measurements indicated the membrane development by a more delayed liquid-liquid demixing in comparison with the PES/NMP/water system, resulting in narrower, longer and denser finger-like structures without the presence of macrovoids (as it was shown in Fig. 1) [50]. In addition, some nanoparticles trapped inside the porous sublayer can be seen in the SEM images of the synthesised membranes, especially in membranes with high concentrations of nanoparticles (marked with red arrows) due to the low dispersion of the entrapped nanoparticles at these conditions and their agglomeration in the matrix structure (see Fig.…”
Section: Morphological Studymentioning
confidence: 65%
“…Furthermore, the shift of the binodal curves in PES/metal nanoparticles membranes in the cloud point measurements indicated the membrane development by a more delayed liquid-liquid demixing in comparison with the PES/NMP/water system, resulting in narrower, longer and denser finger-like structures without the presence of macrovoids (as it was shown in Fig. 1) [50]. In addition, some nanoparticles trapped inside the porous sublayer can be seen in the SEM images of the synthesised membranes, especially in membranes with high concentrations of nanoparticles (marked with red arrows) due to the low dispersion of the entrapped nanoparticles at these conditions and their agglomeration in the matrix structure (see Fig.…”
Section: Morphological Studymentioning
confidence: 65%
“…Several membrane design and surface modification techniques have been carried out to enhance the membrane properties such as plasma treatment [11], addition of pore additives (e.g. polyethylene glycol) [12] and incorporation of inorganic nanoparticles such as clay [13], calcium carbonate [14], CuO [15], carbon nanotube [16,17] and activated carbon [18]. The addition of nanoparticles is known to affect the morphology, porosity, pore size and mechanical properties of the membrane, and provides additional diffusion pathway.…”
Section: Introductionmentioning
confidence: 99%
“…In essence, the contact angle and water uptake provide indications of the hydrophilicity of a membrane. A membrane with high water content and low contact angle is considered hydrophilic (Sadrzadeh and Bhattacharjee 2013). In general (Fig.…”
Section: Water Absorption and Contact-angle Analysismentioning
confidence: 99%