Rational Preparation of Atomically Precise Non-Alkyl Tin-Oxo Clusters with Theoretical to Experimental Insights into Electrocatalytic CO ₂ Reduction Applications

Macrocyclic Inorganic Tin‐Containing Oxo Clusters: Heterometallic Strategy for Configuration and Catalytic Activity Modulation

“…This might be attributed to the fact that Ti 4 + can facilitate cluster charging to promote the CO 2 RR activity. [26] The satisfied stability of these electrodes were confirmed by the well-kept powder Xray diffraction patterns after electrocatalysis and also the basically maintained current density during the catalytic process (Figures S8-S13).…”

“…[23][24][25] Therefore, the construction of non-organotin complexes is highly appealing. Although a few pyrazole stabilized non-alkyl tin-oxo clusters without SnÀ C bonds were recently prepared by us and several lacunary polyoxometalates stabilized inorganic SnÀ O moieties were known, [26][27][28][29][30][31] the preparation of pure inorganic tin-oxo clusters is still very challenging.…”

Molecular bixbyite-like In12-oxo clusters with tunable functionalization sites for lithography patterning applications

“…The recently developed and widely applied coordination delayed hydrolysis (CDH) strategy was hence employed for the growth of InOCs crystals. 11,30 Diethanolamine was selected as the chelate initiator to protect In 3+ ions from violent hydrolysis and also stabilize the produced In-O cores. Accordingly, the self-assembly of InCl3 with diethanolamine in methanol at 100 C for two days gave rise to block crystals of InOC-1.…”

A [Th 8 Co 8 ] Nanocage-Based Metal–Organic Framework with Extremely Narrow Window but Flexible Nature Enabling Dual-Sieving Effect for Both Isotope and Isomer Separation

“…Cages or cage-based compounds present a highly desired porous material for host-guest recognition and separation, due not only to internal-porosity but also window-size adjustment [1][2][3][4][5][6][7][8][9] .…”