1958
DOI: 10.1021/ja01556a078
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Reaction of Biscyclopentadienylcobalt(ii) With Organic Halides

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Cited by 30 publications
(2 citation statements)
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“…Certain olefin complexes in which the EAN for the metal is being exceeded will readily undergo oxidation 0 or other reactions in which less involvement of electrons (and/or ligand atoms) with the metal are observed. The action of CC14 on cobaltocene (32) and (25) serves to illustrate this principle, (LIII). Some of the reactions of nickelocene also follow this principle, such as (LIV) (37), (LV) (19), and (LVI) (51).…”
Section: Future Trendsmentioning
confidence: 99%
“…Certain olefin complexes in which the EAN for the metal is being exceeded will readily undergo oxidation 0 or other reactions in which less involvement of electrons (and/or ligand atoms) with the metal are observed. The action of CC14 on cobaltocene (32) and (25) serves to illustrate this principle, (LIII). Some of the reactions of nickelocene also follow this principle, such as (LIV) (37), (LV) (19), and (LVI) (51).…”
Section: Future Trendsmentioning
confidence: 99%
“…A related trichloromethyl derivative is formed by the reaction of carbon tetrachloride with di-ir-cyclopentadienylcobalt(II) (30). It is red, melts between 79.…”
Section: Although the Reduction Of The Ion To Di--rr-cyclopentadienylmentioning
confidence: 99%