Reactions of fluorine atoms

The kinetics of the reaction F + H2 ? HF + H. A critical review of literature data

“…The results on which the recommendations were based are summarized in Table I. (For other results which are considered to be less accurate, see reviews by Foon and Kaufman [12], Jones and Skolnik [13], and Anderson [14]. ) We made a detailed examination of the publications in which the results summarized in Table I were reported and came to the conclusion that since some of the results are much more accurate than others, the preferred kinetic data should be based mainly on these results.…”

The reaction of active nitrogen with fluoroethylenes

“…From the present observation that addition of H atoms greatly enhances the reactions C2H3F, 1,l-C2H2F2, and C3HF3 with active nitrogen we suggest that hydrogen addition reactions initiate these reactions in the same way as proposed for hydrocarbon reactions (4). A set of possible reactions can thus be proposed for the hydrogen-containing fluorocarbons as shown in reactions [12] to [20].…”

Infrared and EPR Spectroscopic Studies of 2-C2H2F and 1-C2H2F Radicals Isolated in Solid Argon

“…Therefore considerable attention has been given to study of their properties (1). The matrix isolation technique has been a highly successful method for spectroscopic investigations of radical products of chemical reactions.…”

“…This paper is devoted to the study of fluorovinyl radicals formed in the reactions of mobile F atoms with C 2 H 2 molecules. In the gas phase, this reaction leads to the formation of two types of products: [1] It was determined that the dominant channel is the formation of 2-C 2 H 2 F radical (9,10). There are two isomers of this radical, which differ in the location of the F atom with respect to the orbital of unpaired electron:…”