Five bands of the 0-v" progression ( 5 2 v" 2 9) of the A2ni-X2ni system of 35C10 have been rotationally analysed. The results have been combined with data from the absorption spectrum of C10, and new molecular constants are reported. The variation of spin-orbit coupling with internuclear separation has been determined for both states.Une analyse rotationnelle de cinq bandes de la progression G v " ( 5 I v" I 9 ) du systkme A21T,-X21Ti de 35C10 a kt6 faite. Les resultats ont etC combines avec des donnees sur le spectre d'absorption de C10, et on prLsente de nouvelles constantes moleculaires. La variation du couplage spin-orbite avec la distance internucleaire a Cte determinee pour les deux etats.[Traduit par le journal]Can. J. Phys., 54, 1043J. Phys., 54, (1976 Can. J. Phys. Downloaded from www.nrcresearchpress.com by San Diego (UCSD) on 11/18/14For personal use only.
12) Note: An anonymous reviewer suggested the use of a high-temperature H2 treatment to remove adsorbed 02. The experiments reported here show that added oxygen does indeed result in formation of the carboxyl groups from the bonded alkoxyl groups, but that when the system is evacuated at reaction temperatures no reaction takes place. However, the presence of Initially adsorbed oxygen could be the cause of the initial fast reaction observed.
Das Übersichtsreferat befaßt sich u.a. mit der Dissoziation von Fluormolekülen und der Rekombination von Fluoratomen, mit Reaktionen mit H2, HD, Hund Halogen‐, Sauerstoff‐ oder Stickstoff‐enthaltenden Verbindungen.
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