Reactions of halogenated acrylonitrile derivatives with arylsulfinate salts

Miller, Bernard; Kalnins, Malda V.

doi:10.1016/0040-4020(67)85064-6

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1967

2015

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Cited by 7 publications

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“…The reaction of 10 with one molar equivalent of sodium sulfinate salt 2 in refluxing ethanol gave 2-tosylacetonitrile (1) in 42% yield. There is one possible mechanism for this reaction the intermediate in this reaction can't be isolated (Scheme 4) [7].…”

Section: Synthesismentioning

confidence: 99%

“…The uncatalyzed reaction is presumably aided by p-toluenesulfinic acid, produced as the reaction progresses (Scheme 2) [7].…”

Section: Synthesismentioning

confidence: 99%

“…It has been reported that sulfonyl groups in 1,2-dicyano-1,2-disulfonyl-ethylenes (7) are rapidly displaced by alcohols to give α,α-dialkoxy-β-sulfonyl-succinonitriles (9) (Scheme 3) [7].…”

Section: Synthesismentioning

confidence: 99%

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Recent Progress in the Chemistry of 2-Tosylacetonitrile

Fadda

Bayoumy

Elattar

2015

Synthetic Communications

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This review reported a broad overview on the chemistry of 2-tosylacetonitrile which considered as a very reactive synthetic compound. The synthetic methods of synthesis were reported. The reactions of the title compound led to the preparation of a variety of heterocyclic ring systems i.e. five and six membered ring systems containing one or two or three heteroatoms. The reaction mechanisms were discussed. The bibliography includes mainly 124 references.

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Section: Synthesismentioning

confidence: 99%

“…The uncatalyzed reaction is presumably aided by p-toluenesulfinic acid, produced as the reaction progresses (Scheme 2) [7].…”

Section: Synthesismentioning

confidence: 99%