Reactions of Os3(CO)12 with halogens

Candlin, J. P.; Cooper, Julian A.

doi:10.1016/s0022-328x(00)86343-3

Cited by 17 publications

(3 citation statements)

References 3 publications

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“…The sample tube was cooled to -190 °C, evacuated, sealed, and allowed to stand at room temperature for a period of 13 days. A nB NMR (160.44 MHz) spectrum of the sample showed only peaks corresponding to 3,5- Hz) ppm]; these chemical shift values agree well with those calculated by using substituent additivity parameters obtained from ref 12: = -17.4 for B( 1,7), +13.9 for B(3), +15.1 for B(5), and -8.1 for B (6).…”

Section: Methodssupporting

confidence: 83%

Net front-side displacement reactions in a carborane system: halide-exchange reactions among derivatives of closo-2,4-dicarbaheptaborane, 2,4-C2B5H7

Ng¹,

Onak²,

Fuller³

1985

Inorg. Chem.

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Section: Methodssupporting

confidence: 83%

Net front-side displacement reactions in a carborane system: halide-exchange reactions among derivatives of closo-2,4-dicarbaheptaborane, 2,4-C2B5H7

Ng¹,

Onak²,

Fuller³

1985

Inorg. Chem.

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“…A study of the kinetics of the reaction between oS3(co)i2 and chlorine or bromine shows that it is independent of halogen concentration in the range studied, and a reaction scheme to explain this is given. 40 The usefulness of Raman spectroscopy in conjunction with i.r. data in determining the geometry of the nietalatom skeleton in polynuclear carbonyl complexes has been eniphasised, and the above halogenocarbonyl complexes are used as examples.41 A detailed Ranian study of Rus(CO)12 and Os3(CO)12 has also been published.…”

Section: Ph3paucl Reacts Similarly To Give P ~~P a U O S ~( C O ) ~Z ...mentioning

confidence: 99%

“…Ally1 Complexes.-The chemistry of x-ally1 complexes of transition metals has been reviewed.340 x-Ally1 complexes of titaniuni(iI1) can be prepared by reduction of dichlorodicyclopentadienyltitanium(rv) using Grignard reagents in the presence of dienes; the best yield is obtained using 1,3-dienes and allenes do not yield ally1 complexes.341 1,3-Dienes also form x-ally1 complexes acid) t e t r acarbony lir on has been determined by X-ray cry st allogr aphy . 40 The absolute configurations of some olefin complexes of general formula PtCle(olefin)(amine) have been determined by circular d i c h r ~i s m . ~~~ The reactions of buta-1,3-diene with silver tetrafluoroborate409 and bis(acety1acetonato)nickel(II) under reducing conditions410 have been reported.…”

mentioning

confidence: 99%

Chapter 13. Transition-metal carbonyls and organometallic complexes

McGinnety¹,

Mays²

1968

Annu. Rep. Prog. Chem., Sect. A. Gen. Phys and Inorg. Chem.

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THE pattern of this year's review has not been changed from that adopted last year. The task of the reviewers in selecting reference becomes, however more difficult from year to year as the volume of published work increases. We hope we have included most of the more striking advances but there is certainly much interesting work which we have had to omit through lack of space. The most notable increase in effort has been in the field of platinum metal chemistry, and this has undoubtedly been stimulated by the ability of many of these complexes to act as homogenous catalysts in organic reactions. Although, as predicted last year, several new complexes of molecular nitrogen have been prepared, the problem of the catalytic fixation of nitrogen under mild conditions remains unsolved.Among the topics which have been reviewed are: metal carbony1s;l kinetics and mechanism of substitution reactions of metal carbonyls;2 the activation of molecular iiitrogen;3 the chemistry of the rarer platinum metal^;^ metal-metal bonds in transition-metal compounds ;5 organometallic derivatives from metal carbonyls and acetylene compounds;6 catalysis by cobalt carbonyl~;~ and mass spectra of organometallic compounds.* Volume 4 of the 'Annual Surveys of Organoinetallic Chemistry' has appeared,g also a useful comprehensive text book.lO Carbonyls and Hydridocarbony1s.-(a) Mononuclear. The electronic spectra of several neutral and ionic metal hexacarbonyls in the vapour and solution states have been recorded at room temperature. Some of the solution spectra have also been recorded at 7 7 " ~. Calculated molecular orbitals have been used for the purpose of transition assignments and also for a discussion of

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Transition Metal Cluster Compounds

King

1972

Progress in Inorganic Chemistry

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Reactions of Os3(CO)12 with halogens

Cited by 17 publications

References 3 publications

Net front-side displacement reactions in a carborane system: halide-exchange reactions among derivatives of closo-2,4-dicarbaheptaborane, 2,4-C2B5H7

Net front-side displacement reactions in a carborane system: halide-exchange reactions among derivatives of closo-2,4-dicarbaheptaborane, 2,4-C2B5H7

Chapter 13. Transition-metal carbonyls and organometallic complexes

Transition Metal Cluster Compounds

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