Reactive polymers on the basis of functional peroxides

Fleychuk, Roman; Kohut, Ananiy; Hevus, Orest; Voronov, Stanislav

doi:10.1002/masy.200450610

Cited by 4 publications

(2 citation statements)

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“…Surfmers which contain di‐tert‐peroxide groups in lipophilic block have also been described 10. The application of peroxide surfmers during the emulsion and dispersion polymerization permits the immobolization of peroxide groups onto the surface of polymeric particles directly during their formation.…”

Section: Introductionmentioning

confidence: 99%

Novel Peroxide Containing Maleinate Surface‐Active Monomers for Obtaining Reactive Polymers

Borzenkov

Hevus

2012

Macromolecular Symposia

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Novel surface‐active monomers were synthesized by successive treatment of tert‐butylperoxy‐6‐hydroxyhexanoate with maleic anhydride, 1,3‐propane sultone and triethylamine or with maleic anhydride and poly(ethylene glycol) methyl ether. The surface‐active properties of monomers were studied. The critical micelle concentrations (cmc) as well as the surface tension at the cmc were determined for obtained monomers. The synthesized compounds were shown to be suitable reactive surfactants for obtaining styrene latexes.

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Section: Introductionmentioning

confidence: 99%

Novel Peroxide Containing Maleinate Surface‐Active Monomers for Obtaining Reactive Polymers

Borzenkov

Hevus

2012

Macromolecular Symposia

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“…However, such peroxides exhibit high thermal stability that constrains their application [12]. The applying of surfmers with peroxyester groups as comonomers for creating surface functionalized colloidal polymeric systems should also be attractive due to their lower thermal stability.…”

Section: Introductionmentioning

confidence: 99%

Obtaining of Functional Surface Active Monomers Based on tert-Butylperoxy-6-hydroxyhexanoate

Borzenkov¹,

Dolynska²,

Kochubei³

et al. 2011

ChChT

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The interaction of ε-caprolactone with tertbutylhydroperoxide led to tert-butylperoxyhexanoate. Peroxymaleinate has been obtained by the reaction of tert-butylperoxyhexanoate with a maleic anhydride. Functional monomers have been synthesized by reactions of peroxymaleinate with propansultone and polyethylene glycol (PEG). The obtained compounds exhibit surface active properties, reducing a surface tension at the water-air interface.

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Synthesis of Epoxyperoxides and Peroxide Derivatives of -D-Galactopyranose Based Thereon

Fleychuk¹,

Vuytsyk²,

Kohut³

et al. 2020

ChChT

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New epoxide-containing peroxides have been synthesized via the interaction between epichlorohydrin and ditertiary -hydroxyalkyl peroxides. The effect of reaction conditions on both the yield and composition of the reaction products has been established. Through the reactions of either the synthesized epoxide-containing peroxides with 1,2;3,4-di-O-isopropylidene--D-galactopyranose or 6-O-glycidyl-1,2;3,4-di-O-isopropylidene--D-galactopyranose with the -hydroxyalkyl peroxides, new peroxide derivatives with ditertiary and primary-tertiary peroxide groups have been synthesized successfully. The decomposition of the developed substances has been studied by complex thermal analysis and the kinetic parameters of the thermolysis have been determined.

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Reactive polymers on the basis of functional peroxides

Cited by 4 publications

References 0 publications

Novel Peroxide Containing Maleinate Surface‐Active Monomers for Obtaining Reactive Polymers

Novel Peroxide Containing Maleinate Surface‐Active Monomers for Obtaining Reactive Polymers

Obtaining of Functional Surface Active Monomers Based on tert-Butylperoxy-6-hydroxyhexanoate

Synthesis of Epoxyperoxides and Peroxide Derivatives of -D-Galactopyranose Based Thereon

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