Transition metal carbide/nitride (MXenes) have attracted widespread attention in recent years due to their unique structure and excellent electrochemical performance. In addition, MXene materials have adjustable interlayer spacing as well as rich functional groups on the bonding end, which provides great potential to enhance the performance of energy devices. However, three-atoms V 2 Cbased MXene was rarely investigated for memristors and its effects on devices are still unknown. In this work, we synthesized V 2 C MXene and fabricated Ag/V 2 C/TiO 2 /W structural memristors. The advantages of V 2 C on memristors were explored including the coexistence of volatile threshold switching (TS) and non-volatile memory switching (MS) behaviors, low Set and Reset voltages, and small cycle-tocycle and device-to-device variations. Moreover, the space charge limited current (SCLC) model is the dominant switching mechanism. Additionally, two types of synaptic plasticity, i.e., long-term potentiation/depression (LTP/LTD), have been achieved by continuous pulse stimulations. These results in this study are of great significance for disclosing the possibilities of low power electronic synapses with V 2 C. Index Terms-V 2 C MXene, low set and reset voltages, space charge limited current, electronic synapses. I. INTRODUCTION W ITH Moore's Law approaching its end, people are willing to discover some new types of microelectronic devices based on new materials or structures to replace traditional logic devices [1]-[3]. In this circumstance, memristor