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Rearrangement of β‐Alkoxyalkylcarbenes
Abstract: Irradiation of I -diazo-2-methoxy-2-methylpropane (8) results apart from the usual intramolecular insertion reaction leading t o (S), mainly in methyl migration to give 2-methoxy-2-butene (10) ; only traces of 1-methoxy-2-methylpropene ( I l), which is formed by a methoxyl shift, were found.
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1998
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