“…The selection of SMOs, such as SnO 2 , ZnO, WO 3 , NiO, and CuO, plays a pivotal role in determining the sensing performance of such chemiresistive gas sensors. , Among them, ZnO and SnO 2 are both n-type semiconductors and have been widely used as gas sensors to detect different kinds of gaseous compounds. Moreover, constructing ZnO–SnO 2 heterojunctions has been widely accepted as a feasible method to enhance the gas sensing performance. , When metal oxides with different energy band structures are hybridized, heterojunctions (i.e., n–n and p–n) would be formed, resulting in the redistribution of electrons or holes and adjustment of the depletion/accumulation layer of SMOs. − This ultimately manifests as the change of material resistance and surface chemisorbed oxygen species, which significantly improve the gas sensing performance. − However, as far as our current knowledge extends, SMO gas sensors have not yet been employed for the detection of 3-methylbutyraldehyde vapor.…”