Recent advances in ion chromatography: A perspective

Lucy, Charles A.

doi:10.1016/0021-9673(96)00034-9

Cited by 36 publications

(17 citation statements)

References 51 publications

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“…IC exploits the differences in ion exchange affinities of different analytes. Lucy [1] has suggested that the documented use of ion exchange goes back to biblical times: when Moses arrived in Marah after crossing the Red Sea he used a tree to "sweeten" brackish water [2]. While any biological material undoubtedly contains capillaries, we shall confine ourselves here to a less ambitious time frame.…”

Section: Introductionmentioning

confidence: 99%

Capillary ion chromatography

Kubáň

Dasgupta

2004

J of Separation Science

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Section: Introductionmentioning

confidence: 99%

Capillary ion chromatography

Kubáň

Dasgupta

2004

J of Separation Science

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“…developed, they are not appropriate if samples contain more or less ions [1]. For example, cadmium At present, a bifunctional ion-exchange column and manganese co-elute under the optimum Ox (IonPac CS5A) is the most effective analytical eluent conditions (80 mM Ox-100 mM tetramethylcolumn for separating transition metals.…”

Section: Introductionmentioning

confidence: 99%

Retention behavior of transition metals on a bifunctional ion-exchange column with oxalic acid as eluent

Ding

Mou

2001

Journal of Chromatography A

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The common eluents used with a bifunctional ion-exchange column (IonPac CS5A) for separating transition metals are pyridine-2,6-dicarboxylic acid and oxalic acid (Ox). When Ox is used, cadmium and manganese co-elute. Although much 21 21 research has been done to overcome the Cd -Mn co-elution problem, the role of lithium hydroxide in separating the transition metals has received little attention. In this study, it is found that when the Ox concentration is higher than 35 mM, allows the separation of seven metals (Cu , Pb , Co , Mn , Cd , Zn and Ni ) in a single run. The effects of inorganic modifiers such as NaNO , Na SO and Na P O on retention behavior of the metals are also investigated.

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“…Nowadays, IC is being widely used for the analysis of ionic species in pharmaceuticals, detergents, fertilizers, pesticides, soil, plants, drinking water, wastewater etc. [1][2][3][4][5][6][7][8][9][10][11].…”

Section: Introductionmentioning

confidence: 99%

Effect of Methanol in the Wash-Solvent Bottle and the OnGuard Cartridges on the Determination of Different Anions Using Ion Chromatography

Manassra¹,

Khamis²,

Obeidi³

et al. 2012

AJAC

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The effect of using methanol in the flush-solvent bottle of the auto-sampler of Ion Chromatograph on the determination of sulfate ions was studied using AS11-HC 2 mm analytical column. The use of 50% methanol in the flush solvent bottle results in overestimation of sulfate concentration by 18%. However, the use of 10% methanol instead of 50% did not show such error in the determination of sulfate using the same column. Furthermore, the effect of using OnGuard-RP and OnGuard-P cartridges for sample pretreatment on the determination of different anions was also studies using AS14-HC 2 mm analytical column. The results indicate that using OnGuard-RP cartridge caused the concentration of fluoride, bromide, nitrate, phosphate and sulfate ions to be underestimated, whereas the concentration of chloride ions to be overestimated. The error in the determination of fluoride, bromide, nitrate, phosphate sulfate, and chloride was found to be 40.0%, 26.0%, 22.8%, 26.8%, 18.0%, and 25.0% of the certified standard concentration, respectively. It was also found that the use of OnGuard-P cartridge resulted in underestimation of fluoride, chloride, bromide, nitrate, phosphate, and sulfate by 60.0%, 40.0%, 82.0%, 87.2%, 45.2%, and 39.0% of the certified standard concentration, respectively. These findings point out to careful corrections that should be considered in any application of ion chromatography utilizing such sample pretreatment.

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Recent advances in ion chromatography: A perspective

Cited by 36 publications

References 51 publications

Capillary ion chromatography

Capillary ion chromatography

Retention behavior of transition metals on a bifunctional ion-exchange column with oxalic acid as eluent

Effect of Methanol in the Wash-Solvent Bottle and the OnGuard Cartridges on the Determination of Different Anions Using Ion Chromatography

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