Recent advances of perovskite oxide-based cathodes in solid oxide electrolysis cells for CO2 electroreduction

Chen, Jiayi; Gao, Xin; Chen, Xiaodong; Zhen, Zheng; Chen, Ya; Zeng, Xiantai; Cui, Lifeng

doi:10.1016/j.mtphys.2023.101237

Cited by 4 publications

(1 citation statement)

References 125 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…This also implies slower deterioration of the electrode materials and improved selectivity in the reactions with electrogeneration of fewer unwanted byproducts. For these reasons, many ongoing studies focus on the development of cathodic processes especially for environmental protection, , and the advancement of cathode materials for CO 2 and nitrate electroreduction as well as for battery applications. , …”

Section: Introductionmentioning

confidence: 99%

Copper-Decorated Titanium Electrodes: Impact of Surface Modifications of Substrate on the Morphology and Electrochemical Performance

Sotgiu,

De Santis,

Orsini

et al. 2024

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

This study investigates the effect of surface modifications of the titanium substrate on the growth of electrochemically deposited copper. These materials are intended to serve as cathodes in the electroreduction of nitrates in aqueous solutions. Surface modifications included the use of hydrogen fluoride for titanium etching and anodization to promote the growth of a structured titania nanotube array. The effect of an intermediate calcination step for the nanotubes before deposition was assessed along with a comparison to an untreated substrate electrode. The materials were comprehensively characterized by SEM, XRD, contact angle, potentiodynamic tests, EIS, and cyclic voltammetry. Their electrocatalytic ability was tested in the reduction of aqueous solutions containing nitrates. The results reveal that surface finishing impacted the shape and size of the Cu microparticles, as well as the nucleation mechanism enabling a crystalfacet-controllable synthesis. All the materials exhibited microsized copper particles with a spherical shape with some clusters. On the etched titanium surface, a high number of heterogeneous submicroscopic particles were also present. The thermally treated anodized substrate promoted the development of a combination of sparse microparticles corresponding to defect sites in amorphous titanium and the presence of a diffuse coating of octahedral nanosized particles whose growth was promoted by the tetragonal structure of anatase crystals. Electrochemical tests display reduced charge transfer resistance upon copper deposition on the modified substrates, which is indicative of the enhanced conductivity of the coated materials. Additionally, cyclic voltammetry and electrolysis experiments reveal the electrodes' potential for nitrate reduction, showing a better response for the etched titanium substrate (30% nitrate removal, after 2 h at 25 mA cm −2 ).

show abstract

Section: Introductionmentioning

confidence: 99%

Copper-Decorated Titanium Electrodes: Impact of Surface Modifications of Substrate on the Morphology and Electrochemical Performance

Sotgiu,

De Santis,

Orsini

et al. 2024

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

show abstract

Recent Progress in Sr₂Fe_1.5Mo_0.5O_6‐δ‐Based Multifunctional Materials for Energy Conversion and Storage

Sun,

Xu,

Song

et al. 2024

Adv Funct Materials

View full text Add to dashboard Cite

Perovskite oxides, particularly double perovskite oxides, have drawn significant research interest within the fields of solid‐state chemistry and materials science. As a quintessential double perovskite oxide, Sr2Fe1.5Mo0.5O6‐δ (SFM) has unique electronic, magnetic, and catalytic properties. These attributes make it a promising candidate for energy conversion and storage applications. This review offers a comprehensive overview of advancements using SFM across various applications, including solid oxide cells, protonic ceramic cells, and electrocatalysis. Notably, the review highlights emerging optimization strategies that enhance functionality based on a fundamental understanding of the reaction mechanisms. The review concludes by discussing the persistent challenges facing SFM‐based functional materials, as well as their prospects, considering both fundamental research and industrial applications.

show abstract

Synthesis and Evaluation of Nb-Doped Lanthanum Strontium Ferrite Oxide Cathodes with Different Compositions for Solid Oxide Fuel Cells

Behzadnia,

Faradonbeh,

Paydar

2024

J. of Materi Eng and Perform

View full text Add to dashboard Cite

Recent advances of perovskite oxide-based cathodes in solid oxide electrolysis cells for CO2 electroreduction

Cited by 4 publications

References 125 publications

Copper-Decorated Titanium Electrodes: Impact of Surface Modifications of Substrate on the Morphology and Electrochemical Performance

Copper-Decorated Titanium Electrodes: Impact of Surface Modifications of Substrate on the Morphology and Electrochemical Performance

Recent Progress in Sr₂Fe_1.5Mo_0.5O_6‐δ‐Based Multifunctional Materials for Energy Conversion and Storage

Synthesis and Evaluation of Nb-Doped Lanthanum Strontium Ferrite Oxide Cathodes with Different Compositions for Solid Oxide Fuel Cells

Contact Info

Product

Resources

About

Recent advances of perovskite oxide-based cathodes in solid oxide electrolysis cells for CO2 electroreduction

Cited by 4 publications

References 125 publications

Copper-Decorated Titanium Electrodes: Impact of Surface Modifications of Substrate on the Morphology and Electrochemical Performance

Copper-Decorated Titanium Electrodes: Impact of Surface Modifications of Substrate on the Morphology and Electrochemical Performance

Recent Progress in Sr2Fe1.5Mo0.5O6‐δ‐Based Multifunctional Materials for Energy Conversion and Storage

Synthesis and Evaluation of Nb-Doped Lanthanum Strontium Ferrite Oxide Cathodes with Different Compositions for Solid Oxide Fuel Cells

Contact Info

Product

Resources

About

Recent Progress in Sr₂Fe_1.5Mo_0.5O_6‐δ‐Based Multifunctional Materials for Energy Conversion and Storage