Recent applications of Stille reaction in total synthesis of natural products: An update

Boehmite@tryptophan‐Pd nanoparticles: A new catalyst for C–C bond formation

“…It should be noted that there are only few reports describing complexes supported on the surface of boehmite for C–C bond formation . As reported in several reviews, the use of Suzuki, Stille and Heck coupling reactions is indispensable for the synthesis of high‐value chemicals such as natural products, agrochemicals, pharmaceuticals, polymers, biologically active compounds and advanced materials . These reactions benefit from the low toxicity and commercial availability of boronic acid, boronate ester derivatives or triphenyltin chloride and alkene sources …”

Synthesis and Reactivity of Oxazinoindolones via Regioselective 6‐exo‐dig Iodolactonization

“…[33] This popular method has often been used in the synthesis of synthetic natural products. [34] Scheme 8. C-C coupling reactions: Stille, Sonogashira or Suzuki.…”

Successive Pd‐Catalyzed Decarboxylative Cross‐Couplings for the Modular Synthesis of Non‐Symmetric Di‐Aryl‐Substituted Thiophenes

“…Palladium-catalyzed cross-couplings [1][2][3][4][5] are among the most utilized reactions in transition metal-catalyzed carbon-carbon bond formation. Generally, the Stille-Migita and Suzuki-Miyura reactions are the most widely used for the preparation of many organic natural products, [6,7] pharmaceuticals, [8] and agrochemicals. [8,9] While heterocycles are ubiquitous in these fields, oligothiophenes have displayed particular importance in growing industries, such as organic photovoltaic, [10][11][12][13] light-emitting diodes, [14][15][16][17] fluorescence imaging, [18][19][20][21][22] and other organic semiconducting materials.…”