AcknowledgementsFirst and foremost, I would like to thank my principal supervisor, Professor A. Kiet.Tieu., for providing timely and insightful advice, financial and spiritual support. My supervisor's implicit trust in my research abilities not only allowed me to freely pursue my goals, but also gave me an opportunity to learn how to manage time and allocate resources. Special thanks go to Professor Druce Dunne, for his insightful instruction and for all the generous attention and time he devoted to my research work. Tables Table 5.
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AbstractThe objective of this work was to produce near-equiatomic NiTi thin films by filtered arc deposition system (FADS) to improve the cavitation erosion resistance of a steel base working in liquid. First, deposition conditions were optimized in order to obtain near-equiatomic NiTi films. Energy dispersive spectroscopy (EDS) was used to measure the composition of films. It was found that both the substrate bias voltage and arc current affect the compositions of as-deposited NiTi films. X-ray diffractometry (XRD) and transmission electron microscopy (TEM) were used to investigate the microstructures of Ni-rich, Ti-rich and near-equiatomic films. Their thermal behaviours were tested using differential scanning calorimetry (DSC). Atomic force microscopy (AFM), ultra micro-indentation system (UMIS) and Romulus scratch testing were used to measure the roughness, hardness and adhesive force of a near-equiatomic thin film.The cavitation erosion resistance of the near-equiatomic NiTi film was assessed using ASTM Test Method G32. It was found that NiTi thin films showed significantly higher cavitation erosion resistance than 316 austenitic stainless steel. The improved cavitation erosion resistance was attributed to the recoverable deformation associated with pseudoelasticity of the NiTi thin film.The effect of substrate temperature on the properties of NiTi thin films was investigated by preheating substrates to different temperatures (130 C, 300 C, 430 C and 600 C). temperature of 600 C was more resistant to cavitation erosion than films deposited at other bias voltages with a similar substrate temperature.The effect of substrate material on the properties of NiTi thin films was investigated by comparing films on mild steel and on austenitic stainless steel. For similar deposition conditions, the NiTi film deposited on mild steel consisted of B2, B19' and R phases, while the NiTi film on stainless steel was dominated by B2 parent phase. This is probably because the lower thermal conductivity of austenitic stainless steel resulted in a higher deposition temperature.The dominance of the B2 phase for deposition with a high substrate temperature, a high bias voltage and the use of stainless steel substrate was not found to be due to Ni-enrichment of the films, but is consistent with stabilization of the parent phase by possible pick-up oxygen and nitrogen from the chamber atmosphere when the deposition temperature is high.The research program successfully pro...