Recent progress on the interfacial regulation and application of 2D antimonene-based van der Waals heterostructures

Li, Jing; Zhou, Wenhan; Xu, Liqiang; Huang, Yaxin; Zhang, Shengli; Zeng, Haibo

doi:10.1063/5.0103000

Cited by 10 publications

(4 citation statements)

References 97 publications

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“…Nevertheless, nearly all previously reported SAAs focus on d‐block transition metals as single‐atom centers, [ 31 ] the reports on SAAs with main‐group p‐block metal centers are quite limited, whereas the studies on p‐block SAAs for the NO 3 RR are still lacking. Inspired by the p‐block Bi with the high capability to activate the nitrogenous molecules and retard the HER, [ 32 ] while ultrathin materials can be an ideal platform for hosting single atoms, [ 33–35 ] we expect that ultrathin Bi‐based SAAs may be intriguing candidates toward the active and selective NO 3 RR.…”

Section: Introductionmentioning

confidence: 99%

Single‐Atom Bi Alloyed Pd Metallene for Nitrate Electroreduction to Ammonia

Chen

et al. 2023

Adv Funct Materials

182

100

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Electrochemical reduction of nitrate to ammonia (NO 3 RR) holds a great promise for attaining both NH 3 electrosynthesis and wastewater purification. Herein, single-atom Bi alloyed Pd metallene (Bi 1 Pd) is reported as a highly effective NO 3 RR catalyst, showing a near 100% NH 3 -Faradaic efficiency with the corresponding NH 3 yield of 33.8 mg h −1 cm −2 at −0.6 V versus RHE, surpassing those of almost all ever reported NO 3 RR catalysts. In-depth theoretical and operando spectroscopic investigations unveil that single-atom Bi electronically couples with its neighboring Pd atoms to synergistically activate NO 3 − and destabilize *NO on Bi 1 Pd, leading to the reduced energy barrier of the potential-determining step (*NO→*NOH) and enhanced protonation energetics of NO 3 − -to-NH 3 pathway.

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Section: Introductionmentioning

confidence: 99%

Single‐Atom Bi Alloyed Pd Metallene for Nitrate Electroreduction to Ammonia

Chen

et al. 2023

Adv Funct Materials

182

100

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“…Such heterostructures are varied in type and are increasingly being recognized as important in 2D catalysis and materials development. 411,426,[433][434][435][436][437][438][439] Adapted with permission. 378 Copyright 2018, Elsevier.…”

Section: Methodsmentioning

confidence: 99%

Emerging two-dimensional materials: Synthesis, physical properties, and application for catalysis in energy conversion and storage

Xu,

Iqbal,

Wang

et al. 2024

TIMS

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<p>Inorganic, organic, and hybrid two-dimensional (2D) materials are being developed for ever-expanding numbers of applications, though energy and catalysis remain the main drivers of their development. We present overviews of bottom-up and top-down synthetic strategies of such materials and examine manufacturing scalability issues. Mechanical, electrical, and thermal properties and their modulation are highlighted because they are fundamental to the above-mentioned drivers. The burgeoning importance of heterostructures in such materials, particularly for catalysis and electrode design and function is stressed. Detailed attention is given to applications of 2D materials to the electrocatalysis reactions: oxygen reduction, oxygen evolution, hydrogen evolution, carbon dioxide reduction, and nitrogen reduction. Water splitting, carbon dioxide reduction, and nitrogen reduction by photocatalysis are also examined. A perspective of expected advances in the expansion of applications and types of 2D materials, with a focus on heterostructure development, is presented in the conclusion.</p>

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“…To increase the functionality, a conducting layer is necessary for electrical contact in the deposition of epitaxially grown 3D oxide on 2D layered muscovite [70]. Band engineering is possible by applying varied interlayer spacing and tailoring the transition from direct to indirect bandgap [71]. MoO2 with high conductivity can provide a suitable base layer for oxide heteroepitaxy.…”

Section: Outlook and Future Workmentioning

confidence: 99%

Epitaxy of oxide and nitride thin films grown by magnetron sputtering

Lahiji

2023

Linköping Studies in Science and Technology. Licentiate Thesis

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The need for electronic devices with new functionalities has caused research to move in a way to design and utilize materials with high-performance thermoelectricity, widely used in batteries, sensors, and electronic devices. Two-dimensional materials (2D) with unique structures and remarkable properties have been identified to fabricate oxide heteroepitaxy. The PrefaceThis licentiate thesis is part of my Ph.D. studies in the Energy Materials unit in the Thin Film

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Recent progress on the interfacial regulation and application of 2D antimonene-based van der Waals heterostructures

Cited by 10 publications

References 97 publications

Single‐Atom Bi Alloyed Pd Metallene for Nitrate Electroreduction to Ammonia

Single‐Atom Bi Alloyed Pd Metallene for Nitrate Electroreduction to Ammonia

Emerging two-dimensional materials: Synthesis, physical properties, and application for catalysis in energy conversion and storage

Epitaxy of oxide and nitride thin films grown by magnetron sputtering

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