Self-excited oscillations have the advantages of absorbing energy from a stable environment and Self-control; therefore, Self-excited motion patterns have broader applications in micro devices, autonomous robots, sensors and energy-generating devices. In this paper, a Self-sustained curling liquid crystal elastomer (LCE) film-mass system is proposed on the basis of electrothermally responsive materials, which can realize Self-oscillation under a steady-state current. Based on the contact model and dynamic LCE model, a nonlinear dynamics model of LCE film in steady-state circuits is developed and numerical calculations are carried out using the Runge–Kutta method. Through numerical calculations, it is demonstrated that LCE film-mass systems have two motion patterns in steady-state circuits: namely, a Self-oscillation pattern and a stationary pattern. Self-sustained curling of LCE film originates from the fact that the energy absorbed by the system exceeds the energy dissipated due to the damping effect. In addition, the critical conditions for triggering Self-oscillation and the effects of several key dimensionless system parameters on the amplitude and period of Self-oscillation are investigated in detail. Calculation results show that the height of electrolyte solution, gravitational acceleration, elastic modulus of LCE film, limit temperature, curvature coefficient, thermal shrinkage coefficient and damping factor all have a modulating effect on the amplitude and period of Self-oscillation. This research may deepen the understanding of Self-excited oscillation, with promising applications in energy harvesting, power generation, monitoring, soft robotics, medical devices, and micro and nano devices.