“…[b] dppz À1600 [26] n.d. À6.22 [27] À2.96 [27] [25] Angewandte Chemie those of dppz, 2, or 3, and thus 5 and 6 are expected to be better hole-transporting materials. The electrochemical data show that 6 has the smallest band gap energy of the compounds studied, and the relative energies of its HOMO and LUMO suggest that it favors transport of both holes and electrons.…”