“…With the rapid rise in data traffic over wireless infrastructures, the conventional radio frequency (RF) wireless technology struggles to meet the increasing demand due to the shortage of available RF spectra and limited bandwidth . In the meantime, optical wireless communication (OWC) offers an unlicensed and secure bandwidth spanning the ultraviolet (UV) to infrared wavelengths, providing a new pathway for uninhibited growth in higher-speed and low-latency data transmission contributing to the Internet of things (IoT), Internet of underwater things (IoUT), and light-fidelity (Li-Fi). − Color-converting phosphors play an essential role in the OWC system. They allow the transmitter (i.e., laser diode (LD) or light-emitting diode (LED)) to function in white-light illumination with a high color rendering index (CRI) or improve the responsivity of the silicon-based photoreceiver for solar-blind UV communication. , However, conventional materials used in visible-light communication (VLC) are centered mainly on ceramic, perovskite, and organic emitters ,,− that require complex synthesis processes, high cost of fabrication, toxicity, and poor tunability, which hinder their continuous development and commercialization. , Therefore, the field of architectural design and fabrication of low-cost, high-modulation bandwidth, and reliable light communication materials is becoming one of the most attractive research avenues for materials scientists, physicists, and engineers.…”