Abstract. Urban aerosol measurements are necessary to establish associations between
air pollution and human health outcomes and to evaluate the efficacy of air
quality legislation and emissions standards. The measurement of urban
aerosol particle size distributions (PSDs) is of particular importance as
they enable characterization of size-dependent processes that govern a
particle's transport, transformation, and fate in the urban atmosphere. PSDs
also improve our ability to link air pollution to health effects through
evaluation of particle deposition in the respiratory system and inhalation
toxicity. To inform future measurements of urban aerosol observations, this
paper reviews and critically analyzes the current state of knowledge on
urban aerosol PSD measurements by synthesizing 737 PSD observations made
between 1998 to 2017 in 114 cities in 43 countries around the globe.
Significant variations in the shape and magnitude of urban aerosol number
and mass PSDs were identified among different geographical regions. In
general, number PSDs in Europe (EU) and North America, Australia, and New
Zealand (NAAN) are dominated by nucleation- and Aitken-mode particles. PSDs
in Central, South, and Southeast Asia (CSSA) and East Asia (EA) are shifted
to larger sizes, with a meaningful contribution from the accumulation mode.
Urban mass PSDs are typically bimodal, presenting a dominant mode in the
accumulation mode and a secondary mode in the coarse mode. Most PSD
observations published in the literature are short-term, with only 14 %
providing data for longer than 6 months. There is a paucity of PSDs
measured in Africa (AF), CSSA, Latin America (LA), and West Asia (WA),
demonstrating the need for long-term aerosol measurements across wide size
ranges in many cities around the globe. Geographical variations in urban aerosol effective densities were also
reviewed. Size-resolved urban aerosol effective density functions from 3 to
10 000 nm were established for different geographical regions and intra-city
sampling locations in order to accurately translate number PSDs to mass
PSDs, with significant variations observed between near-road and urban
background sites. The results of this study demonstrate that global
initiatives are urgently needed to develop infrastructure for routine and
long-term monitoring of urban aerosol PSDs spanning the nucleation to coarse
mode. Doing so will advance our understanding of spatiotemporal trends in
urban PSDs throughout the world and provide a foundation to more reliably
elucidate the impact of urban aerosols on atmospheric processes, human
health, and climate.