Size dependence of magnetic properties
of Sm0.43Ca0.57MnO3 nanoparticles
with average size of 15–60 nm has been investigated. Charge
ordering, characteristic for the bulk form of this material, was found
to be gradually suppressed with decreasing particle size and fully
disappearing in 15 nm nanoparticles. Onsets of ferromagnetic contributions
to the magnetization appear below 90 K, independently on the particle
size, while spontaneous magnetization at 10 K increases with decreasing
particle size. Magnetic hysteresis loops exhibit size dependent exchange
bias effect manifested by horizontal H
EB and vertical M
EB shifts, appearing after
field cooling. Variation of H
EB and M
EB shows opposite size dependences; H
EB decreases while M
EB increases with decreasing particle size. For large 60 nm particles, H
EB decreases monotonously with increasing temperature,
while for the smallest 15 nm particles it shows surprising nonmonotonic
temperature dependence. Size and temperature dependences are discussed
in terms of magnetic coupling between antiferromagnetic cores and
shells containing ferromagnetic clusters in a frustrated spin configuration.