facilitates the full potential of photovoltaic devices (PVs), whose record efficiency exceeds 29%. [4] In addition, developing the PSCs' roll-to-roll process allows us to fabricate large-area PSCs at low costs. [5] Consequently, PSCs can compete with other PV technologies in the market regarding device performance and manufacturing cost. However, almost all PVs are installed in harsh outdoor conditions where the temperature and humidity vary throughout the year; their reliability also plays a vital role in determining their levelized cost of electricity. Despite the importance of reliability, the inherent poor stability of PSCs makes it difficult for them to fulfill commercialization standards. The short lifetimes of PSCs are mainly attributed to the poor chemical stabilities of the perovskite and buffer layers. Intensive studies have been conducted to prevent perovskite films from reacting with oxygen and moisture, including encapsulation, [6] novel device structures, [7] and buffer engineering. [8] Last of all, several groups suggested general design rules for stable PSCs. [9] Nevertheless, the large-sized, perovskite PV-based energy harvesting system, consisting of parallel and series-connected PSCs, will face other stabilization issues as its size increases to obtain an appropriate voltage and current. Mechanical stress resistance, [10] the fireproofing of PSCs, [11] and stability against electrical stress [12] should be considered. Significantly, the reliability of PSCs against electrical stress becomes a more critical factor because they are supposed to connect a power grid. FromThe electrical stability of perovskite solar cells (PSCs) will play an essential role in their commercialization because field-installed PSCs frequently operate under non-ideal voltages. Particularly, an instantaneous extremely high voltage (IEHVs) from electro-static discharge will be applied to PSCs due to friction in roll-to-roll processes. In addition, lightning strikes and surges from grids are plausible sources of IEHVs to field-installed PSCs. Hence, the effect of IEHVs on PSCs is systematically investigated and a robust device structure is suggested. An IEHV severely deteriorates PSCs by destroying their diode characteristics. Physical and chemical damage from IEHVs to the interface between the perovskite film and buffer layers causes increased recombination losses and series resistance. To reinforce the heterointerface, a well-known surface defect passivation method is adopted, adding excessive PbI 2 to perovskite films. The excessive PbI 2 , mainly located at the interface, successfully protects PSCs from IEHV. Moreover, inserting well-established defect passivation layers, C 60 , and phenethylammonium iodide into the interface of a perovskite film improves the device's stability against IEHV. Therefore, interface defect passivation is viable for stable PSCs against abnormal electrical stress. It is believed that this study will provide fundamental insights for designing electrically reliable PSCs, which is crucial for...