GaN vertical LED on metal alloy substrate (VLEDMS) has been successfully realized for wavelength spectrum from near UV to green color. Owing to the vertical structure and highly heat-conductive metal alloy substrate, VLEDMS exhibits an ultra high brightness and excellent reliability suitable for solid state lighting (SSL) application. A brightness of 80Lm/W using 450 nm chip mixed with yellow phosphor was achieved by optimization of LED structure epitaxy, chip process and packaging. Using 405 nm chip with polychromatic phosphor a 50 Lm/W white light with color rendering index better than 90 was obtained. We also can get very good uniform correlated color temperature from package with VLEDMS chip.