Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences

Kanatzidis, Mercouri G.; Poeppelmeier, Kenneth R.; Bobev, Svilen; Guloy, Arnold M.; Hwu, Shiou‐Jyh; Lachgar, Abdessadek; Latturner, Susan E.; Raymond, Rudy; Schaak, E.; Sevov, Slavi C.; Stein, Andreas; Dąbrowski, B.; Greenblatt, Martha; Grey, Clare P.; Jacobson, Allan J.; Keszler, Douglas A.; Li, Jing; Subramanian, M. A.; Xia, Younan; Çağın, Tahir; Häußermann, Ulrich; Hughbanks, Timothy; Mahanti, S. D.; Morgan, Dane; Seo, Dong‐Kyun; Spaldin, Nicola A.; Buhro, William E.; Giammar, Daniel E.; Hollingsworth, Jennifer A.; Johnson, David C.; Nozik, A. J.; Peng, Xiaogang; Bedard, Robert L.; Brese, N. E.; Cao, Guang Sheng; Dhingra, Sandeep S.; Kagan, Cherie R.; Mitzi, David B.; Geselbracht, Margret J.; Lisensky, George C.; Lufaso, Michael W.; Maggard, Paul A.; Michael, O'Keeffe; Wilkinson, Angus P.; Loye, Hans‐Conrad zur; Egami, T.; Greedan, John E.; Hodges, J. P.; Martin, James D.; Parise, John B.; Toby, B.H.; Vanderah, Terrell A.; Burns, Peter C.; Chan, Julia Y.; Meyer, Anne E.; Murray, Christopher B.; Ramirez, A. P.; Ward, Michael D.; Yu, Lan; Alario-Franco, M.Á.; Battle, Peter D.; Bein, Thomas; Cahill, Christopher L.; Halasyamani, P. Shiv; Maignan, A.; Seshadri, Ram

doi:10.1016/j.progsolidstchem.2007.02.002

Cited by 64 publications

(19 citation statements)

References 260 publications

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“…Such technologies include adsorption used for water and exhaust-gas treatment as well as photocatalytic processes for contaminant degradation. Nanoscale sizes can also influence the chemical reactivity of materials by the predominance of nearsurface regions with compositions distinct from bulk regions and increasing the contribution of interfacial free energy to the free energy of dissolution-precipitation reactions [7]. NZVPs have demonstrated and exhibited high reactivity in remediating many hazardous compounds such as non-aqueous phase liquids and heavy metals.…”

Section: Environmental Cleanup: Benefits and Limits Of Nano-based Tecmentioning

confidence: 99%

Nanoparticles Restrictions in Environmental Cleanup

Snousy¹,

Mf²

2017

Nano Res Appl

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Environmental contamination with a variety and mixed pollutants are a problematic issue worldwide. If the contaminated sites are left without any satisfactory remediation, it leads to the successive threaten of ecosystems, then human life. So, applications of nanotechnology in environmental remediation are encouraged because of the novel properties (e.g. special structure, very large surface area and greater reactivity), whereas, ''Nano'' may be more than just ''small''. Also, environmental nanotechnology restraint is due to lack of full understanding characterization, fate and transport of such ultrafine materials in the environment. The objective of this work is to point major challenges facing environmental nanoscience and urges developing eco-friendly techniques to ensure good quality of life.

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Section: Environmental Cleanup: Benefits and Limits Of Nano-based Tecmentioning

confidence: 99%

Nanoparticles Restrictions in Environmental Cleanup

Snousy¹,

Mf²

2017

Nano Res Appl

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“…[15][16][17][18] Lack of a generally applicable rational synthesis planning framework is considered the missing link for realization of computer-designed functional inorganic materials. 1,4,19 While a reaction involving two or more solids may eventually become rate-limited by diffusion of reacting species towards the reaction zone as the product thickens, [20][21][22] the emergent product phase at the onset of the reaction is often controlled by nucleation. This concept of phase selection through nucleation has the potential to enable design of rational synthesis routes for inorganics.…”

Section: Introductionmentioning

confidence: 99%

Rational Solid-State Synthesis Routes for Inorganic Materials

2021

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Rational solid-state synthesis of inorganic compounds is formulated as catalytic nucleation on crystalline reactants, where contributions of reaction and interfacial energies to the nucleation barriers are approximated from high-throughput thermochemical data, and structural and interfacial features of crystals, respectively.Favorable synthesis reactions are then identified by a Pareto analysis of relative nucleation barriers and phase-selectivities of reactions leading to the target. We demonstrate the application of this approach in reaction planning for solid-state synthesis of a range of compounds, including the widely-studied oxides LiCoO 2 , BaTiO 3 and YBa 2 Cu 3 O 7 , as well as other metal oxide, oxyfluoride, phosphate and nitride targets. Pathways for enabling retrosynthesis of inorganics are also discussed. File list (2) download file view on ChemRxiv SynthesisPlanning_Manuscript_v2.pdf (4.71 MiB) download file view on ChemRxiv SynthesisPlanning_Manuscript_SI_v2.pdf (3.39 MiB)

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Section: Introductionmentioning

confidence: 99%

Rational Solid-State Synthesis Routes for Inorganic Materials

Aykol¹,

Montoya²,

Hummelshøj³

2021

Preprint

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Rational solid-state synthesis of inorganic compounds is formulated as catalytic nucleation on crystalline reactants, where contributions of reaction and interfacial energies to the nucleation barriers are approximated from high-throughput thermochemical data, and structural and interfacial features of crystals, respectively. Favorable synthesis reactions are then identified by a Pareto analysis of relative nucleation barriers and phase-selectivities of reactions leading to the target. We demonstrate the application of this approach in reaction planning for solid-state synthesis of a range of compounds, including the widely-studied oxides LiCoO2, BaTiO3 and YBa2Cu3O7, as well as other metal oxide, oxyfluoride, phosphate and nitride targets. Pathways for enabling retrosynthesis of inorganics are also discussed.

show abstract

Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences

Cited by 64 publications

References 260 publications

Nanoparticles Restrictions in Environmental Cleanup

Nanoparticles Restrictions in Environmental Cleanup

Rational Solid-State Synthesis Routes for Inorganic Materials

Rational Solid-State Synthesis Routes for Inorganic Materials

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