“…Low resistivity ionic conductor sodium-beta -alumina has been extensively studied due to its applications in sodium-sulfur batteries [1][2][3][4] and sodium-nickel chloride batteries (ZEBRA batteries) [4,5]. Synthesis of sodium-beta -alumina can be roughly categorized into two types: solid-state reaction processes and novel soft-chemistry routes such as sol-gel processing [6][7][8], coprecipitation [9], alkoxide hydrolysis [10], and solution combustion techniques [11], etc.…”