flow rate, nozzle diameter, and collector distance), as well as physicochemical properties of the fluid, induce different EHD effects, each one unique in terms of potential, limitations, and applicability. [7] A schematic showing selected examples of EHD techniques, and a summary grouping their general parameters are provided in Figure 1 and Table 1, respectively.By taking advantage of Rayleigh-Plateau instabilities, electrospraying and drop-on-demand EHD approaches allow particle generation, generally using lowconcentration polymer solutions. Electrospraying allows significant material volume processing but offers limited control in terms of size, shape, and particle placement accuracy (Figure 1a). [26] Drop-on-demand, in contrast, deals with smaller volumes but increases the control over the processed particle and printing resolution (Figure 1b). [27] As described by Taylor in 1969, by preventing Rayleigh-Plateau instabilities through the increase of fluid molecular entanglements, it is possible to achieve a continuous jet. [28,29] In electrospinning, small diameter fibers are achieved by taking advantage of bending or "whipping" instabilities, induced by large surface charge density. The non-woven mats obtained using electrospinning have been of great interest for nanotechnology research, however, accurate fiber deposition is challenging (Figure 1c). [29] In EHD writing (electrowriting [EW]), lower voltages prevent these whipping instabilities, and the EHD phenomenon results in the sustaining of a fluid jet at low flow rates, allowing for accurate control over fiber dimension and deposition (Figure 1e). [28] The control of material placement is a crucial feature for additive manufacturing since this permits the precise deposition of fibers forming 2D layers, which can be repeated to produce highly complex highresolution 3D structures. This becomes even more crucial for biomedicine where a key goal is to mimic the biological environment of native tissue to support and guide cellular growth or understand tissue regeneration mechanisms. [30,31] The use of jet-deflecting auxiliary electrodes allows the control of bending or "whipping" instabilities to achieve the accurate patterning of nanofibers, providing an intermediate approach between electrospinning and EW [32] (Figure 1d).EHD techniques have primarily focused on processing polymeric materials, although metals and ceramics have also been explored. [33,34] Polymeric melts provide a low-toxicity alternative avoiding the use of hazardous solvents, decreasing the material consumption, and reducing processing variables (e.g., evaporation), but have a limited selection of available materials. [35] Solution-based EHD processing can process a wider range of materials, however, commonly used organic solvents are often Among the various electrohydrodynamic (EHD) processing techniques, electrowriting (EW) produces the most complex 3D structures. Aqueous solution EW similarly retains the potential for additive manufacturing well-resolved 3D structures, while providing n...