With the development of international cooperation, South Africa (SA) has been China’s largest trading partner in Africa for several consecutive years. China and SA can build the digital “Belt and Road” to modernize the manufacturing system locally and optimize process control by benchmarking with the best-in-class manufacturers in each country. In this research, an evaluation technology of manufacturer intelligence regarding the selection of decision support system (DSS) of smart manufacturing technologies, analyzing China–South Africa relations, is described. Firstly, the three keys aspects that enable the technologies of DSS are discussed in detail. Then, one key technology, the manufacturers’ intelligent evaluation system with 15 indexes, was built. The indexes and their measurements are also proposed. Finally, a fusion method based on boosting with multi-kernel function (online sequential extreme learning machine based on boosting, Boosting-OSELM) is introduced. The purpose of Boosting-OSKELM is to combine several weak learners into a strong learner (lower mean square error, MSE) through an acceptable time delay. Finally, the case study is presented to demonstrate the improvement on the MSE and process time, showing a relative MSE improvement of 96.19% and a relative time delay ratio of 31.46%. Totally, the largest contribution of the proposed evaluation method in this study is the conversion of the history data saved by the manual scoring method into knowledge in accessible MES and resealable time delay, which will free up the expert workforce in the entire process. We expect this paper will help future research in this field.