With the rapid development of electric vehicles (EVs) around the world, debates have arisen with regard to their impacts on people’s lifestyles and urban space. Mining spatio-temporal patterns from increasingly smart city sensors and personal mobile devices have become an important approach in understanding the interaction between human activity and urban space. In this study, we used location-based service data to identify EV owners and capture the distribution of home and charging stations. The research goal was to investigate that how the urban form in regions under rapid urbanization is driven by EV use, from a geographical perspective. Using a case study of the expanding metropolis of Beijing, GIS-based spatial statistical analysis was conducted to characterize the spatial-pattern of the homes of EV owners as well as their charging preferences. Our results indicate that the spatial clustering of the homes of EV owners in non-urban central areas—suburban areas—is significantly higher than that in urban central areas. According to the records of visits to charging stations, the spatial interaction distance between the dwellings of EV owners and their visits to charging stations exhibits significant distance attenuation characteristics. 88% of EV owners in this research travels within 40 km (Euclidean distance) between housing and charging stations. At the same time, there were significant differences in the spatial patterns between working days and non-working days which are affected by commuting activities. The three types of urban spatial interaction patterns were identified and categorized by visualization. This transformation to EV use in the city influences several aspects of people’s decisions and behaviors in life. Understanding the impacts will provide valuable information for the development of EVs and their implications in the electrification of transportation, smart planning, and sustainable urbanization.