Perovskite solar cells (PSCs) have
emerged as a cost-effective
solar technology in the past years. PSCs by three-dimensional hybrid
inorganic–organic perovskites exhibited decent power conversion
efficiencies (PCEs); however, their stabilities were poor. On the
other hand, PSCs by all-inorganic perovskites indeed exhibited good
stability, but their PCEs were low. Here, the development of novel
all-inorganic perovskites CsPbI2Br:xNd3+, where Pb2+ at the B-site is partially heterovalently
substituted by Nd3+, is reported. The CsPbI2Br:xNd3+ thin films possess enlarged
crystal sizes, enhanced charge carrier mobilities, and superior crystallinity.
Thus, the PSCs by the CsPbI2Br:xNd3+ thin films exhibit more than 20% enhanced PCEs and dramatically
boosted stability compared to those based on pristine CsPbI2Br thin films. To further boost the device performance of PSCs, solution-processed
4-lithium styrenesulfonic acid/styrene copolymer (LiSPS) is utilized
to passivate the surface defect and suppress surface charge carrier
recombination. The PSCs based on the CsPbI2Br:xNd3+/LiSPS bilayer thin film possess reduced charge extraction
lifetime and suppressed charge carrier recombination, resulting in
14% enhanced PCEs and significantly boosted stability compared to
those without incorporation of the LiSPS interface passivation layer.
All these results indicate that we developed a facile way to approach
high-performance PSCs by all-inorganic perovskites.