including the bandwidth, photoresponsivity, and photoconductive gain. [5,6] To overcome these limitations, graphene hybrid photodetectors incorporating photo sensitive materials such as single crystals, [7] 2D materials, [8] organic polymers, [9] colloidal quantum dots, [10,11] and silicon [12] have been widely adopted to enhance the photoresponse. For example, methylammonium triiodideplumbate (CH 3 NH 3 PbI 3 ) perovskite incorporated with graphene yielded a planar heterojunction photodetector with a broad spectral response from 405 to 800 nm. [13] Moreover, a hybrid graphene phototransistor adopting organic semiconductor poly (3-hexylthiophene) (P3HT) achieved a high photoresponse up to 10 5 A W −1 . [9] Despite that the combination of photosensitive layers and graphene has proved to be an effective strategy to enhance the performance of phototransistors, [14][15][16][17][18] the absence of an internal built-in electric field using a single type of light-sensitive layers leads to relatively low photoresponsivity for photodetection.Recently, the combination of a PN heterojunction into graphene optoelectronic devices as the absorption layer has been considered as an emerging means to enhance the responsivity and photoconductive gain. [19,20] The internal built-in electric field within the PN heterojunction enables efficient dissociation for excitons. [19] Meanwhile, different absorption wavelengths of the PN layers with proper band alignment can lead to unique bidirectional photoresponse, enabling the extension of the photo detection bandwidth. [21] Recently, a pentacene planar heterojunction was employed to integrate with graphene to fabricate a high-performance transistor, showing bidirectional photoresponse at different wavelength regions with an ultra-wide spectrum detection from 405 to 1550 nm. [22] Meanwhile, a vertical graphene-C 60 -graphene heterojunction in a 250 × 250 photodetector array was assembled to realize a high photoresponsivity of 3.4 × 10 5 A W −1 (λ = 405 nm, i.e., visible) with bidirectional photocurrent responses. [23] In spite of the considerable progress made in the last decades to achieve highperformance detection for visible and ultraviolet light, most of the graphene phototransistors are still limited to low photoresponsivity at the near-infrared (NIR) region.
Graphene-organic heterojunction phototransistorshave great potential to achieve sensitive photoresponse owing to the excellent absorption of organic layers and fast charge transport in graphene. However, the photoresponse of most graphene-based phototransistors is limited within visible light region with narrow bandwidth and poor sensitivity in the near-infrared (NIR) region. Herein, a graphene-organic NIR phototransistor is fabricated by integrating an organic heterojunction layer composing of phthalocyanine molecules and fullerene C 60 onto the graphene channel. The phototransistor exhibits a high photoresponsivity of 2.2 × 10 3 A W −1 under 850 nm irradiation with the power density of 35.4 mW cm −2 (V ds = 1 V). Meanwhile, a ...