devices/sensors, [10][11][12] and green architectures. [13] However, for homogenous material deformability, shape reconfiguration has relied on mold-assisted techniques that increase complexity. The ancient art of origami has been recently endowed with a new vitality with regard to 3D shape-reconfigurable materials. [14,15] An origami pattern consists of foldable and non-foldable creases with an anisotropic deformability that enables shape guiding and functionalities without molding. [7,16,17] This is fully compatible with shapereconfigurable materials because it incorporates the benefits of 2D simplicity, high throughput, and space conservation. It also provides a guided folding mechanism for shape reconfiguration. However, origamis that are based on nonrigid patterns require heavy pressurization to maintain a specific geometry. [18,19] Thus, to entirely forgo this process, an origami material must integrate two factors. First, in a predetermined origami pattern, the kinematic deformation must be solely restricted to the plastically folding creases, while the non-folding regions remain undeformed. Second, the origami material must exhibit repeatable "self-locking," where the deployed structure can be spontaneously fixed at a particular configuration without pressure. However, removal of the self-locking should enable re-shaping. By introducing the selflockable origami pattern, versatile shape-configurable materials are possible without assisting equipment.A self-lockable polymer origami that can significantly change shape along a foldable and non-foldable pattern, and spontaneously fix a specific geometry, can be fabricated via bi-and multi-layer assemblies [8,20] and lateral curing. [21] However, these structures usually suffer from delamination between layers and non-repeatable shape changes. Another method uses origami made from shape-memory polymers. [22,23] In this case, shapereconfiguration can be realized via stimuli-responsive elasticity, which subsequently eliminates stimuli that fix the geometry in a particular state. However, the elastically deforming into temporary shapes still need continuous external force load to remain its geometries, impeding the complexity of on-demand 3D shape-reconfigurability. Recent progress in covalent adaptable network polymers [24,25] offers strategies for polymeric origami that standard approaches cannot achieve. Because of bonding exchange reactions within a dynamic network topology, crosslinked polymers exhibit stimuli-responsive plasticity. [26,27] The Shape-reconfigurable materials are crucial in many engineering applications. However, because of their isotropic deformability, they often require complex molding equipment for shaping. A polymeric origami structure that follows predetermined deformed and non-deformed patterns at specific temperatures without molding is demonstrated. It is constructed with a heterogeneous (dynamic and static) network topology via light-induced programming. The corresponding spatio-selective thermal plasticity creates varied deformabili...