2017
DOI: 10.1080/00958972.2017.1278572
|View full text |Cite
|
Sign up to set email alerts
|

Review: an overview of recent developments in coordination chemistry of polypyrazolylmethylamines. Complexes with N-scorpionate ligands createdin situfrom pyrazole derivatives and zerovalent metals

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
4
1

Citation Types

0
17
0

Year Published

2019
2019
2022
2022

Publication Types

Select...
6

Relationship

1
5

Authors

Journals

citations
Cited by 30 publications
(17 citation statements)
references
References 128 publications
0
17
0
Order By: Relevance
“…This multipodal, tridentate organic ligand formed in situ can be called an "impaired" scorpionate, an analogue of poly(pyrazolyl)borate ligands, containing only two, instead of three, pyrazole groups. Generally, complexes with an N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)amine (L D ) ligand are much less numerous than those with tripodal teradentate ligands [16,18,19,22]. Only nine complexes with N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)amine have been reported in CCDC, and therein six complexes were synthesised by us [16,18,19,21,22].…”
Section: Discussionmentioning
confidence: 99%
See 3 more Smart Citations
“…This multipodal, tridentate organic ligand formed in situ can be called an "impaired" scorpionate, an analogue of poly(pyrazolyl)borate ligands, containing only two, instead of three, pyrazole groups. Generally, complexes with an N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)amine (L D ) ligand are much less numerous than those with tripodal teradentate ligands [16,18,19,22]. Only nine complexes with N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)amine have been reported in CCDC, and therein six complexes were synthesised by us [16,18,19,21,22].…”
Section: Discussionmentioning
confidence: 99%
“…We have previously reported the one pot synthesis and physicochemical characterizations of complexes containing N,N,N-tris (3.5-dimethylpyrazol-1-ylmethyl)amine ligands (L S ) [6,[13][14][15][16], which is an analogue of original poly(pyrazol-1-yl) borates called scorpionates [17]. Complexes with N,N,N-tris(3.5-dimethylpyrazol-1-ylmethyl)amine ligands (L S ) showed high antiproliferative activities against a panel of human cancer cells [6,15,16]. The nature of ligands and their architectures significantly determines the properties of resulting complex species [6,[13][14][15][16][18][19][20][21].We have also previously found that cationic-anionic (Co/Zn and Co/Cd) complexes containing N-scorpionate ligands (such as N,N,N-tris (3.5-dimethylpyrazol-1-ylmethyl)amine (L S )), express substantial antiproliferative potency [6,15].…”
Section: Introductionmentioning
confidence: 99%
See 2 more Smart Citations
“…To this aim, significant efforts have been devoted to tailor electronic and steric ligands properties and to accommodate various metal ions in their binding pockets as to prepare organometallics or coordination compounds featured by targeted catalytic requirements . In particular, the preparation of multidentate N‐ligands (N > 2) and the study of their metal ion coordination behavior is a well‐developed research area in contemporary organometallic chemistry . The introduction of aromatic N‐containing heterocycles like pyridine, triazole, or pyrazole, has contributed to expand the variety of N‐multidentate backbones.…”
Section: Introductionmentioning
confidence: 99%