2020
DOI: 10.1149/1945-7111/ab847f
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Review—An Unpredictable Hazard in Lithium-ion Batteries from Transition Metal Ions: Dissolution from Cathodes, Deposition on Anodes and Elimination Strategies

Abstract: While various techniques have been developed to address the safety issues in lithium-ion batteries, there remain unknown mechanisms that induce hazards, leaving challenges in developing reliable lithium-ion systems. In this manuscript, an unpredictable hazard originated from the dissolution of transition metal ions from cathodes and their deposition on anodes is presented. The cathodes in currently commercialized lithium-ion batteries contain transition metal ions, which might dissolve in electrolytes, transpo… Show more

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Cited by 99 publications
(85 citation statements)
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References 87 publications
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“…Pada beberapa area kerja dengan risiko sedang hingga tinggi digunakan teknik engineering control yaitu mekanisme Standard Operating Procedure (SOP), penyusunan jam kerja, dan pengontrolan penggunaan Alat Pelindung Diri (APD) sehingga potensi bahaya dapat dikendalikan. Penerapan Personal Protective Equipment dilaksanakan dengan disiplin dalam pemakaian alat pelindung diri merupakan hal yang penting untuk area kerja risiko tinggi serta risiko ekstrim sehingga dapat mencegah kecelakaan (Li, 2020). Menurut Boruthnaban et al (2021) mengatakan bahwa penting untuk diimplementasikannya teknik pengendalian risiko hazard agar dapat menurunkan risiko bahaya di tempat kerja.…”
Section: Pembahasanunclassified
“…Pada beberapa area kerja dengan risiko sedang hingga tinggi digunakan teknik engineering control yaitu mekanisme Standard Operating Procedure (SOP), penyusunan jam kerja, dan pengontrolan penggunaan Alat Pelindung Diri (APD) sehingga potensi bahaya dapat dikendalikan. Penerapan Personal Protective Equipment dilaksanakan dengan disiplin dalam pemakaian alat pelindung diri merupakan hal yang penting untuk area kerja risiko tinggi serta risiko ekstrim sehingga dapat mencegah kecelakaan (Li, 2020). Menurut Boruthnaban et al (2021) mengatakan bahwa penting untuk diimplementasikannya teknik pengendalian risiko hazard agar dapat menurunkan risiko bahaya di tempat kerja.…”
Section: Pembahasanunclassified
“…Same with LIB cathode materials, transition metal (TM) ions are essential in SIB cathodes as the redox reaction centers, and one of the biggest challenges for the TM‐based cathodes is the capacity and power fading especially at elevated temperatures, which is directly associated with the TM dissolution from the cathode materials 44 . TM dissolution not only alters the surface structure of the cathode materials, but more importantly, the dissolved TM ions, albeit <1% of the total amount, deposit on the surface of the negative electrode, which thickens the SEI by catalyzing the reductive decomposition of the electrolyte, resulting in irreversible Li consumption and impedance increase 45 . Generally, TM dissolution is due to the acidic species (eg, HF, HClO 4 ) generated from the oxidation decomposition of organic liquid electrolytes.…”
Section: Temperature Dependence Of Sibsmentioning
confidence: 99%
“…136 Owing to their extensive use worldwide, secondary batteries pose safety issues and environmental hazards that need to be addressed. 137 Several studies investigated the application of bacterial-polymer-based electrolytes in metal-ion batteries as a novel biocomponent (Table 1). Regarding cyclability, the Coulombic efficiency remained at 100 and 90% capacity retention after over 330 cycles.…”
Section: Applicationsmentioning
confidence: 99%