Modular multilevel converters (MMCs) represent the forefront of power converter technology, with wide-ranging applications across diverse industries. Over recent decades, substantial research and development efforts have been dedicated to enhancing MMCs’ performance. A significant challenge in power conversion processes is the presence of total harmonic distortion (THD) in output waveforms, which can have adverse effects on electrical equipment. In response, extensive studies have been conducted to address THD-related challenges by refining the control and operation of MMCs. This study investigates the effect of the amplitude modulation index (Ma) on the total harmonic distortion (THD) in nine-level MMC output waves. For this, a standard three-phase and nine-level MMC model was built and simulated in MATLAB/ Simulink environment, and the Ma value was shifted between 0.1 and 1.5. The output current and voltage waves were analyzed, and the optimal limits for the Ma values yielding the lowest THD values were determined. The simulation outcomes reveal a crucial Ma range between 0.6 and 1.2, where THD is significantly minimized. Ma values below 0.6 introduce significant harmonic distortion in the voltage waves, while values surpassing 1.2 lead to appreciable harmonic distortion in the current wave. This study contributes valuable insights for engineers and researchers and aids in the refinement of MMC control strategies and the mitigation of THD-related challenges in power systems.