In
this study, the optimized expanded vermiculite (EVM) was used
as the matrix and a series of novel form-stable composite phase change
materials (fs-CPCMs) were prepared by the physical impregnation method.
The results showed that acid leaching and organic intercalation EVM
had a better package effect (≥74.9 wt %) and heat storage capacity
(≥139.2 J/g) compared with EVM, which showed a good optimization
effect, revealing that proper modification treatment was beneficial
to the improvement of the thermophysical properties of composite PCMs.
Nonisothermal crystallization kinetics demonstrated that the EVM matrix
was beneficial to reduce the nucleation activation energy (ΔE
a) of PEG, and the optimized EVM could further
reduce the ΔE
a, which effectively
improved the crystal nucleation process of PEG. However, the matrix
would restrict the crystal growth process of PEG, which had certain
adverse effects. Moreover, XRD, TGA, and cycle tests showed that the
prepared novel fs-CPCMs had excellent chemical stability, thermal
stability, and cycle reliability. This research provided a certain
theoretical reference and technical support for the preparation of
mineral-based organic composite phase change materials with high heat
storage capacity and excellent phase change behavior.