La 2 O 2 CO 3 -WO 3 composites were here proposed as unconventional photocatalysts for the removal of phthalates in water. The high sorption properties of the lanthanum dioxide carbonate allowed a strong adsorption of the phthalates which facilitated the following solar photocatalytic degradation, further boosted by the addition of small amounts of WO 3 (1 wt %). On the contrary, a higher content of WO 3 had a detrimental effect due to the covering of the surface sites of La 2 O 2 CO 3 that inhibited the adsorption process. This double mechanism of strong adsorption-photocatalytic oxidation led, after 6 h of solar irradiation, to 67 % and 63 % dimethyl phthalate and di(2ethylhexyl)phthalate degradation, respectively. The phthalates were degraded to less persistent pollutants that, however, were completely removed after 9 h of irradiation. The La 2 O 2 CO 3 -WO 3 system appears promising for its application in the removal of the emerging contaminants from water.[a] E.