Extensions of the Standard Model that include vector-like quarks commonly also include additional particles that may mediate new production or decay modes. Using as example the minimal linear σ model, that reduces to the minimal SO(5)/SO(4) composite Higgs model in a specific limit, we consider the phenomenology of vector-like quarks when a scalar singlet σ is present. This new particle may be produced in the decays T → tσ, B → bσ, where T and B are vector-like quarks of charges 2/3 and −1/3, respectively, with subsequent decay σ → W + W − , ZZ, hh. By scanning over the allowed parameter space we find that these decays may be dominant. In addition, we find that the presence of several new particles allows for single T production cross sections larger than those expected in minimal models. We discuss the observability of these new signatures in existing searches.