Synthesis and magnetorheology of suspensions of cobalt particles with tunable particle size M T López-López, P Kuzhir, A Meunier et al. Abstract. The aim of this study is a preparation and application of inorganic coating on the surface of carbonyl iron particles. The two step solvothermal synthesis provides core-shell CI/ZnO rod-like morphology. Compact coating of particles has a slightly negative impact on their magnetic properties (measured for magnetic field strength in the range from 0 to 213 mT); however, there is a suitable magnetorheological performance investigated under oscillatory shear, suitable to be applied in real applications.
IntroductionSuspensions consisting of the solid magnetic particles dispersed in the liquid medium usually silicone oil, changing their basic rheological quantities (viscosity, viscoelastic moduli) upon external magnetic fields are called generally Magnetorheological (MR) [1][2][3][4][5][6][7][8][9]. Nowadays, material exhibiting this behaviour repeatedly can find various applications as shock absorbers [5] or also in the medical application in the local cancer hyperthermia treatment [9]. In order to obtain the highest MR efficiency of the suspensions usually ferromagnetic particles with low value of coercivity dispersed in medium with negligible magnetic properties are employed [11,12]. Furthermore, sedimentation stability is another factor significantly influences the MR efficiency. MR suspensions exhibit poor stability, especially when the carbonyl iron is employed as a dispersed phase. Therefore, various techniques were utilized to obtained sufficient sedimentation properties such as bidispersed or dimorphic MR fluids [11,[13][14][15]. Promising approach consists of preparation of the core-shell based magnetic particles, where a magnetic core is coated with a suitable layer decreasing the overall density of the core-shell particles and enhancing interactions between particles and liquid medium [16,17].In the preceding study [18] another approach based on inorganic-inorganic CI/ZnO core-shell particle silicone oil suspension was developed. The sedimentation stability as well as thermo-oxidation one were significantly enhanced and also improved MR efficiency under steady state conditions were confirmed.In this study, the viscoelastic behaviour of the CI/ZnO was discovered in detail. While the results from steady state conditions provide mostly information about the MR efficiency, the viscoelastic ones describing the behaviour close to the real-life applications.