Rhodium(I) complexes with N-heterocyclic carbene ligands: synthesis, biological properties and catalytic activity in the hydrosilylation of aromatic ketones

Hamdi, Naceur; Slimani, Ichraf; Mansour, Lamjed; Alresheedi, Faisal; Özdemır, İsmaıl; Gürbüz, Nevin

doi:10.1080/00958972.2021.1992400

Journal of Coordination Chemistry

2021

DOI: 10.1080/00958972.2021.1992400

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Rhodium(I) complexes with N-heterocyclic carbene ligands: synthesis, biological properties and catalytic activity in the hydrosilylation of aromatic ketones

Naceur Hamdi

Ichraf Slimani

Lamjed Mansour

et al.

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Cited by 4 publications

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Bidentate Ru(II)‐NC Complexes as Catalysts for Transfer Hydrogenation of Ketones with Ethanol

Li,

Lian,

Wang

et al. 2024

Asian J Org Chem

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We developed a bidentate Ru(II)‐NC‐catalyzed transfer hydrogen reaction of ketones using ethanol (EtOH) as the hydrogen source under a weak base condition. The control experiments suggested that the reaction proceeds via the Ru‐H mechanism and yields ethyl acetate as the only byproduct. The deuterium‐labeling experiments further showed that hydrogen evolved from the CH2 and OH groups. The results provide a new weak base system for the transfer hydrogen reaction of ketones using ethanol as the hydrogen donor.

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Bidentate Ru(II)‐NC Complexes as Catalysts for Transfer Hydrogenation of Ketones with Ethanol

Li,

Lian,

Wang

et al. 2024

Asian J Org Chem

View full text Add to dashboard Cite

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Synthesis, crystal structures, DFT calculations, and catalytic application in hydrosilylation of acetophenone derivatives with triethylsilane of novel rhoduim-N-heterocyclic carbene (NHCs) complex

Hassen

Zouaghi

Slimani

et al. 2022

Journal of Molecular Structure

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Selenium-N-heterocyclic carbene (Se-NHC) complexes with higher aromaticity inhibit microbes: synthesis, structure, and biological potential

Kamal

Iqbal

Bhatti

et al. 2022

Journal of Coordination Chemistry

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Rhodium(I) complexes with N-heterocyclic carbene ligands: synthesis, biological properties and catalytic activity in the hydrosilylation of aromatic ketones

Cited by 4 publications

References 63 publications

Bidentate Ru(II)‐NC Complexes as Catalysts for Transfer Hydrogenation of Ketones with Ethanol

Bidentate Ru(II)‐NC Complexes as Catalysts for Transfer Hydrogenation of Ketones with Ethanol

Synthesis, crystal structures, DFT calculations, and catalytic application in hydrosilylation of acetophenone derivatives with triethylsilane of novel rhoduim-N-heterocyclic carbene (NHCs) complex

Selenium-N-heterocyclic carbene (Se-NHC) complexes with higher aromaticity inhibit microbes: synthesis, structure, and biological potential

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