Pure and Zn-doped BaTi 0.9 Sn 0.1 O 3 ceramics are prepared via the conventional solid state reaction method. The microstructures, dielectric properties, and diffuse transition of BaTi 0.9 Sn 0.1 O 3 ceramics with 0, 0.2, 1 and 2 at.% Zn have been investigated. The results indicate that zinc ions enter the unit cell maintaining the perovskite structure of solid solution. Grain size of BaTi 0.9 Sn 0.1 O 3 ceramics sharply decreases after doping ZnO. However, once ZnO content is more than 0.2 at.%, the average grain size of Zndoped BaTi 0.9 Sn 0.1 O 3 ceramics slightly increases with the increasing of ZnO content. The addition of zinc leads to the increase of the Curie temperature. The diffuseness of the phase transition of Zn-doped BTS ceramics decreases with the increase of Zn content, which may be due to grain size effect.