Cover: Different morphological aspects of poly(vinyl acetate) particles produced through suspension polymer-ization are shown. When produced by conventional free radical polymerization, final particles present an irregular oval morphological aspect, due to combination of the high shear rates and high reaction rates. When small amounts of the RAFT chain transfer agent are used, final particles present the usual spherical morphology of beads produced in suspension, due to the lower reaction rates and consequently longer relaxation times to dissipate shear tensions. Further details can be found in the article 453 Full Paper: Moving horizon estimation is an optimization-based filter that can address non-linear and constrained systems. A monitoring procedure with statistical parameters estimated by the autocovar-iance least-squares technique is proposed and validated with experimental emulsion polymerization reaction data. The estimation results are compared with gravimetric analysis and the effect of the initial estimate is also evaluated, showing that the procedure is robust.