Robust heterostructures of a bimetallic sodium–zinc metal–organic framework and reduced graphene oxide for high-performance supercapacitors

Abstract

A robust 2D heterostructure of heterobimetallic Na/Zn-MOF and rGO can be a promising alternative electrode material for next generation supercapacitors.

Boosting the performance of broccoli-like Ni-triazole frameworks through a CNTs conductive-matrix

“…Notably, the maximum capacitance value can also be compared with that of recent reports on MOFs-based electrodes. [6][7][8]11,16,17,[30][31][32][33] These results suggest that introduction of CNTs not only inuences the exterior morphology and thus further affects the surface area, the interface effect and synergy effect of the composite, but also indeed improves the resulting electrochemical performances through its morphology discrepancy. 20,21 Aer carefully checking from the table, the second discrepancy is generated, that is, the distinct rate capability.…”

Functionalized Cu‐MOF@CNT Hybrid: Synthesis, Crystal Structure and Applicability in Supercapacitors

“…The continuously enhanced CV integrated area under the curves for IITI‐1 /CNT/GCE along with the amplified current response without any noticeable signal loss at higher scan rates, reveal its good charge storage characteristics and high rate ability. This escalated charge storage and related properties is the outcome of the positive synergistic properties between 2D Cu‐MOF and highly conducting CNT . In conclusion, the promoted charge storage characteristics in IITI‐1 /CNT/GCE can be assigned as a synergistic alliance of pseudocapacitive IITI‐1 /GCE and double layer capacitive CNT/GCE.…”

“…Owing to increase in engineering of commercial compact electronic devices, the demand for high energy storage in miniature form has increased enormously . In this regard, the electrochemical storage device such as supercapacitors are the most prominent candidate for highly efficient energy storage applications compared to fuel cell and lithium‐ion batteries, because of its high columbic efficiency, quick charge‐discharge process, outstanding environment friendliness, excellent cycling stability and reversibility, which can fulfill the demand for energy consumption and makes them superior to batteries having ordinary power density and cycle life span.…”

ZnII and CuII-Based Coordination Polymers and Metal Organic Frameworks by the of Use of 2-Pyridyl Oximes and 1,3,5-Benzenetricarboxylic Acid

“…[Zn(Hbtc)(H 2 pyaox) 2 ] n (2) and [Cu(Hbtc)(HmpKo)] n (4) are rare examples of coordination polymers containing a 2-pyridyl oxime either in its neutral or anionic form. Note that H 3 btc has been employed in the field of MOFs and has led to the synthesis and characterization of many such species, including the MOFs HKUST, MIL-100, etc., [ 39 , 43 , 68 , 69 , 70 , 71 , 72 , 73 , 74 , 75 , 76 , 77 ], however its combination with an oximic ligand is essentially unexplored.…”