Role of Active Complexes of Selected Thiopurine Derivatives with Bi(III) Ions Related to Kinetics and Mechanism of the Electrode Process in the Surfactant Presence

Nosal‐Wiercińska, Agnieszka; Kaliszczak, W.

doi:10.1007/978-3-030-51905-6_36

Cited by 2 publications

(1 citation statement)

References 34 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…À ions to the destruction of the water structure and the fact that they only slightly adsorb on the electrode surface is an added value and very relevant to the phenomena occurring at the electrode/solution interface. The previous studies have shown a significant effect of changes in water activity [10] and the presence of organic substances on the mechanism and kinetics of electroreduction of Bi(III) ions, [11][12][13][14][15][16] which has advanced the interpretation of the mechanism of the "cap-pair" effect. [15] The aim of the present study was to investigate the electroreduction process of In(III) ions and in the presence of acetazolamide as a function of changes in water activity.…”

Section: Introductionmentioning

confidence: 98%

Catalysis of Indium Ion Electroreduction in the Presence of Acetazolamide in Chlorates(VII) Solutions with Varied Water Activity

Nosal‐Wiercińska,

Martyna,

Szabelska

et al. 2024

ChemPhysChem

View full text Add to dashboard Cite

The influence of acetazolamide (ACT) on the kinetics and the mechanism of electroreduction of In(III) ions as a function of changes of the water activity was investigated using electrochemical methods (DC, SWV, CV and EIS, CV). The multi‐step mechanism of the electroreduction process should take into account the dehydration step of indium ions and the presence  of In ‐ ACT (,,cap‐pair” effect) active complexes, mediating electron transfer, located in the adsorption layer.  Differences in the electrode mechanism in the presence of ACT were observed for higher chlorates(VII) concentrations  (above 4 mol‧dm‐3 chlorates(VII)) reflected by a lack of step wise nature of the electrode process. The highest catalytic activity was observed in 4 mol·dm‐3 chlorates(VII).

show abstract

Section: Introductionmentioning

confidence: 98%

Catalysis of Indium Ion Electroreduction in the Presence of Acetazolamide in Chlorates(VII) Solutions with Varied Water Activity

Nosal‐Wiercińska,

Martyna,

Szabelska

et al. 2024

ChemPhysChem

View full text Add to dashboard Cite

show abstract

Influence of mixed 2-thiocytosine–ionic surfactants adsorption layers on kinetics and mechanism of Bi(III) ions electro reduction: use of the nanostructured R-AgLAFE

2022

View full text Add to dashboard Cite

The nanostructured cyclically refreshable liquid amalgam film silver-based electrode (R-AgLAFE) was applied to study of the Bi(III) electrode process in the presence of 2-thiocytosine and selected ionic surfactants. The application of voltammetrictechniques (SWV, CV, DC), as well as electrochemical impedance spectroscopy (EIS) allowed the determination of the kinetic which in turn, defined the 2-thiocytosine catalytic effect and also their correlation in the presence of surfactants. The presence of mixed 2-thiocytosine-CTAB and 2-thiocytosine-SDS adsorption layers affects the mechanism and kinetics of Bi(III) ions electro-reduction process in chlorate(VII). CTAB and SDS change the dynamics of the catalytic impact of 2-thiocytosine on Bi(III) ions electro reduction. In both cases, the Bi–(RS–Hg) complex plays a key role, as it is the 2-thiocytosine that dominates in the establishment of the adsorption equilibria of the studied mixed adsorption layers.

show abstract

Role of Active Complexes of Selected Thiopurine Derivatives with Bi(III) Ions Related to Kinetics and Mechanism of the Electrode Process in the Surfactant Presence

Cited by 2 publications

References 34 publications

Catalysis of Indium Ion Electroreduction in the Presence of Acetazolamide in Chlorates(VII) Solutions with Varied Water Activity

Catalysis of Indium Ion Electroreduction in the Presence of Acetazolamide in Chlorates(VII) Solutions with Varied Water Activity

Influence of mixed 2-thiocytosine–ionic surfactants adsorption layers on kinetics and mechanism of Bi(III) ions electro reduction: use of the nanostructured R-AgLAFE

Contact Info

Product

Resources

About