This study compares the ozone valleys over the Tibetan Plateau (TP) and the Rocky Mountains (RM) using the ERA5 reanalysis data set. The dynamical transport of the ozone over these two regions is analyzed using the Lorenz circulation decomposition method. The ozone content valley over TP is observed around 200–50 hPa (upper troposphere and lower stratosphere, or UTLS), and that over RM is around 300–100 hPa. It is shown that the TP ozone content is smaller than that over RM. By analyzing the spatiotemporal distribution of the ozone content and the general circulation, the anticyclone over Southern Asian (SAH) plays a significant role in existence of the TP ozone valley, and the ozone content flux reaches its maximum in July. Large‐scale terrain and related general circulation determine the ozone valley appearance. Further analysis suggests that stationary transport has a larger impact on the ozone valley formation than the transient transport. The transport by the zonal circulation nearly cancels out most of that by the meridional circulation, due to the fact that the zonal transport magnitude is nearly equal to the meridional transport. The transport center over the RM is much weaker than that over the TP. Furthermore, the contrasts between transient and stationary transports are less evident over RM than over TP. The eddy‐driven stationary ozone transport flux significantly impacts the development of the two low ozone centers across these large terrains.