This analysis explains the magneto-hydrodynamic flow on Williamson nanofluids previous stretching surface surrounded by the permeable media. The apt magnetic field was suggested for the angle of the axial direction of the flow. Anyhow, this flow phenomenon was characterized into the added heat source/sink and conjunction of radiating heat. The impacts of convective heating and viscous heating by expanding surface were again the significant feature of the analysis. This originality arises by the combination of the cross-diffusion effects of reverse behavior on the thermophoresis and Brownian motion. This form sketched into the aforesaid phenomenon was modified into the nonlinear ordinary form by the appropriate assumptions on comparison transformations. Therefore, the sets of equations were controlled for the numerical access using Lobatto-IIIa collocation method applicable to this Matlab bvp4c shooting process. This parametric performance of many components about their statistical values was given numerical imitations graphically by the rate coefficients in tabular forms. The validation and the compliance of the current result were acquired by the past study on the specific case. Further, the significant results of this analysis were: This non-Newtonian Williamson parameter combination of that magnetizing property diminishes the fluid velocities. In addition, the important influence of both viscosity parameter and radiation parameter of heating process was noted.