“…Furan‐2‐carboxylate has been used as a key component in the synthesis of a variety of pharmaceuticals, such as antibacterial, [8] antioxidant, [9] antimicrobial, [9–10] anticancer, [11] antifungal, [12] anti‐gluconeogenesis, [13] and antitumor [14] . Some compounds containing a furan ring are already available as drugs, such as amiodarone, [15] azimilide, [16] ceftiofur, [17] cefuroxime, [18] dantrolene, [19] diloxanide furoate, [20] dronedarone, [21] fumoxicillin, [22] furazolidone, [23] geiparvarin, [24] mirfentanil, [25] nalfurafine, [26] nifuratel, [27] nifurtimox, [28] rofecoxib, [29] roseophilin, [30] and vilazodone [31] . Thus, developing an efficient and comfortable approach to synthesizing furan‐2‐carboxylate derivatives with high purities is important.…”