The utilization of photovoltaic (PV) cleaning robots has proven to be an effective method for maintaining the conversion efficiency of utility-scale PV power plants by mitigating the impact of dust accumulation. However, ensuring the safe operation of these robots, resembling tanks in appearance, particularly in wet working conditions, relies heavily on their adherence to PV panels. This study focuses on assessing the slip resistance of candidate materials coated on endless polyurethane timing belts, which are equipped on PV cleaning robots to enable the efficient cleaning of uneven and misaligned PV arrays. A novel apparatus is proposed to evaluate the coefficient of static friction (COSF) of slip specimens, considering factors such as outsole patterns, area density, and shore hardness. The results highlight the significant influence of shore hardness and area density on the slip resistance of the specimens. Based on the findings, it is recommended to design track grooves with hexagon or zigzag patterns and maintain a low area density (e.g., 0.44 g·mm−2) to ensure the safe operation of PV cleaning robots, irrespective of the working conditions they encounter. By addressing the slip resistance challenge, this research contributes to the overall efficiency and reliability of PV cleaning robots, enhancing their performance in maintaining clean and optimal PV panel surfaces.