Hexaferrites
have a wide range of technological applications as
well as a rich and complicated structural chemistry, with iron oxide
layers inducing highly anisotropic ferrimagnetism that remains intact
to high temperatures (>400 K). Most hexaferrites (i.e., M-type
BaFe12O19) contain the dominant magnetic vectors
normal
to the hexagonal planes forming hard ferrimagnets, while the much
less common Y-type investigated here typically contains the ferrimagnetic
vectors in the iron oxide planes, creating soft ferrimagnets suitable
for RF applications. To study the structural chemistry and magnetism
of this less common hexaferrite phase, single crystals of K2Co4V9O22 (I) and Ba2Fe11Ge2O22 (II) were prepared. The structure of these compounds is a derivative
of the sophisticated mineral greenwoodite, having a complex assembly
of transition metal octahedra and tetrahedra, notably featuring Kagomé
layers in spinel-type blocks that are magnetically isolated from one
another. In particular, compound II provides a pathway
to developing iron-rich hexaferrites where the magnetic ions are not
diluted by site substitution of nonmagnetic ions. This results in
an exceptionally high magnetic ordering temperature of 855 K to a
canted antiferromagnetic state.